Because [H+] and [OH-] in aqueous solutions span an enormous range (roughly 1 M down to about 10−14 M), it is far more convenient to work on a logarithmic scale. pH is defined as pH=−log10[H+], and pOH similarly as pOH=−log10[OH−]; each single pH unit represents a ten-fold change in [H+]. The two are linked through water's own ionization equilibrium, H2O(l)+H2O(l)⇌H3O+(aq)+OH−(aq), whose equilibrium constant, the ionic product of water Kw=[H3O+][OH−], equals 1.0×10−14 at 298 K (rising at higher temperature, since water's ionization is endothermic). Taking logarithms of Kw=[H3O+][OH−] gives the compact and very widely used relation pH+pOH=14 at 298 K. This immediately fixes the three regions of the pH scale: a neutral solution (pure water) has [H3O+]=[OH−]=1.0×10−7 M and pH exactly 7; an acidic sol …