Q.Anhydrous sodium sulphate dissolves in water with the evolution of heat. What is the effect of temperature on its solubility?
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Start your 14-day free trial to unlock the full solution →Step 1. The question states that anhydrous sodium sulphate (Na2SO4) dissolves in water WITH the evolution of heat -- meaning the dissolution process is exothermic (releases heat to the surroundings).
Step 2. By Le Chatelier's principle, adding heat to a system at equilibrium (i.e. raising temperature) pushes the equilibrium in whichever direction ABSORBS that added heat.
Step 3. Since dissolution here releases heat (is exothermic), it is the REVERSE process -- crystallisation (solute coming back out of solution) -- that would absorb heat if it happened. So raising the temperature favours crystallisation over further dissolution. …
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