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Problems · Problem 2.2

Q.The Henry's law constant of methyl bromide (CH₃Br), is 0.159 mol L⁻¹ bar⁻¹ at 25⁰C. What is the solubility of methyl bromide in water at 25⁰C and at pressure of 130 mmHg?

Maharashtra MsbshseTextbookSubjectiveImportance★★★★★
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130 mm Hg = 0.171 atm = 0.173 bar; S = KHPK_H P = 0.159 × 0.173 = 0.0275 M.

Step 1. Convert the pressure to bar: P=130 mm Hg×1760 mm Hg/atm=0.171P = 130\ \text{mm Hg} \times \dfrac{1}{760\ \text{mm Hg/atm}} = 0.171 atm, and 0.171 atm×1.013 bar/atm=0.1730.171\ \text{atm} \times 1.013\ \text{bar/atm} = 0.173 bar. …

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