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Physics · Ch 15 — Structure of Atoms and Nuclei

De Broglie's Explanation

15.6.4

De Broglie's Explanation

Chapter 14 established that matter, not just light, has a dual wave-particle nature: every material particle has an associated wave, with wavelength given by the de Broglie relation λ=h/p\lambda=h/p. De Broglie's key suggestion was to stop picturing the orbiting electrons inside an atom as tiny particles travelling along a track, and instead picture each one as a STANDING WAVE wrapped around its circular orbit -- directly analogous to the standing waves that form on a fixed string or inside a closed pipe (Chapter 6), which can only vibrate at certain special (resonant) wavelengths.

For a standing wave to exist stably around a closed circular path, the wave must join up smoothly and consistently with itself after one full trip around the circle -- meaning the orbit's total circumference must contain a WHOLE number of wavelengths, with no partial wavelength left over to cause destructive interference. For the nth orbit (radius rnr_n), this condition is written 2πrn=nλn2\pi r_n=n\lambda_n, where n = 1, 2, 3, ... must be a positive integer. …

Figure 15.5Fig.15.5: Standing electron wave for the 4th orbit
Fig. 15.5 — Fig.15.5: Standing electron wave for the 4th orbit

Drawn by us to help you understand the concept clearly, and verified to make sure it's accurate. For exams, practice from your textbook's own diagram.

What this figure shows. A circular orbit (drawn as a circle of some radius r4r_4, representing the electron's fourth Bohr orbit, n=4) with a wave pattern drawn wrapped around its circumference instead of a plain circular line: the wave completes exactly four full oscillations (four crests and four troughs, i.e. exactly n=4n=4 complete wavelengths) as it goes once around the full circle, so that the wave joins up smoothly with itself with no discontinuity where it meets its own starting point. The figure's purpose is to make visually concrete the standing-wave condition 2πrn=nλn2\pi r_n=n\lambda_n -- only orbits where a whole number of wavelengths fit exactly around the circumference can sustain a stable, self-reinforcing standing wave; any non-integer number …