Physics · Ch 15 — Structure of Atoms and Nuclei
Radii of the Orbits
Radii of the Orbits
Bohr's first two postulates together are enough to work out the size of each allowed orbit. Let the electron (mass ) move with speed in a circular orbit of radius , the nth stable orbit. The second postulate fixes its angular momentum as .
The first postulate says the centripetal force keeping the electron in this circular orbit comes from the electrostatic attraction between the electron (charge ) and the nucleus (charge , for an atom with atomic number Z): .
These are two equations in the two unknowns and . Eliminating between them gives the orbit radius directly: -- showing immediately that the radius grows as the SQUARE of the principal quantum number n, so higher orbits are very much larger than lower ones, not just slightly larger. Eliminating instead gives the orbital speed, , which DECREASES as n increases -- electrons in higher, larger orbits move more slowly, not faster. …
Worked out. A direct application of for hydrogen (Z=1), asking for the radius when n=3. Substituting the Bohr radius nm and gives nm, illustrating both the formula itself and how quickly the orbit radius grows with the principal quantum number -- the third orbit is already about nine times larger than the first (ground-state) orbit, since radius scales as rather …