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Physics · Ch 15 — Structure of Atoms and Nuclei

Radii of the Orbits

15.6.1

Radii of the Orbits

Bohr's first two postulates together are enough to work out the size of each allowed orbit. Let the electron (mass mem_e) move with speed vnv_n in a circular orbit of radius rnr_n, the nth stable orbit. The second postulate fixes its angular momentum as mevnrn=nh2πm_ev_nr_n=\frac{nh}{2\pi}.

The first postulate says the centripetal force keeping the electron in this circular orbit comes from the electrostatic attraction between the electron (charge −e-e) and the nucleus (charge +Ze+Ze, for an atom with atomic number Z): mevn2rn=14πϵ0Ze2rn2\frac{m_ev_n^2}{r_n}=\frac{1}{4\pi\epsilon_0}\frac{Ze^2}{r_n^2}.

These are two equations in the two unknowns vnv_n and rnr_n. Eliminating vnv_n between them gives the orbit radius directly: rn=n2h2ϵ0πmeZe2r_n=\frac{n^2h^2\epsilon_0}{\pi m_eZe^2} -- showing immediately that the radius grows as the SQUARE of the principal quantum number n, so higher orbits are very much larger than lower ones, not just slightly larger. Eliminating rnr_n instead gives the orbital speed, vn=Ze22ϵ0hnv_n=\frac{Ze^2}{2\epsilon_0hn}, which DECREASES as n increases -- electrons in higher, larger orbits move more slowly, not faster. …

Misc Ex.15.1Radius of the 3rd orbit of the electron in hydrogen atom

Worked out. A direct application of rn=a0n2r_n=a_0n^2 for hydrogen (Z=1), asking for the radius when n=3. Substituting the Bohr radius a0=0.053a_0=0.053 nm and n2=9n^2=9 gives r3=9×0.053=0.477r_3=9\times0.053=0.477 nm, illustrating both the formula itself and how quickly the orbit radius grows with the principal quantum number -- the third orbit is already about nine times larger than the first (ground-state) orbit, since radius scales as n2n^2 rather …