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Choose the Best Answer · Q12

Q.The IUPAC name of (CH3)(Br)CH-CH(CH3)-COOH, i.e. CH3-CH(Br)-CH(CH3)-COOH, is

a) 2-Bromo-3-methylbutanoic acid
b) 2-methyl-3-bromobutanoic acid
c) 3-Bromo-2-methylbutanoic acid
d) 3-Bromo-2,3-dimethylpropanoic acid
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Step 1. CH3-CH(Br)-CH(CH3)-COOH is a 4-carbon chain: C1 = COOH, C2 = CH(CH3), C3 = CH(Br), C4 = CH3.

Step 2. COOH is the principal group and must get the lowest possible locant, so numbering starts from that end -- C1 = COOH is fixed.

Step 3. Reading off: methyl substituent at C2, bromo substituent at C3.

Step 4. Citing substituents alphabetically (bromo before methyl): 3-bromo-2-methylbutanoic acid. …

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