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Choose the Best Answer · Q5

Q.The IUPAC name of the compound H3C-CH2-CH(CH3)-CH(CH2CH3)-CH2-CH2-CH2-CH3 (an octane chain bearing a methyl branch on the third carbon and an ethyl branch on the fourth carbon, counting from the H3C end) is

a) 2,3-Diemethylheptane
b) 3-Methyl-4-ethyloctane
c) 5-ethyl-6-methyloctane
d) 4-Ethyl-3-methyloctane
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Step 1. Number the drawn chain left to right: C1(H3C)-C2(H2)-C3(bearing a CH3 branch)-C4(bearing a C2H5 branch)-C5-C6-C7-C8(CH3), an 8-carbon (octane) chain.

Step 2. Check numbering from the right instead: the branches would fall at locants 5 (ethyl) and 6 (methyl) -- {5,6} is higher than {3,4}, so left-to-right numbering wins.

Step 3. With locants fixed as ethyl-4, methyl-3, the substituents must be cited ALPHABETICALLY in the name: 'ethyl' comes before 'methyl'. …

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