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Choose the Best Answer · Q30

Q.Assertion: CH3-C(COOC2H5)=CH-COOH is 3-carbethoxy-2-butenoic acid.
Reason: The principal functional group gets the lowest number, followed by the double bond (or) triple bond.

(a) both the assertion and reason are true and the reason is the correct explanation of assertion.
(b) both assertion and reason are true and the reason is not the correct explanation of assertion.
(c) assertion is true but reason is false
(d) both the assertion and reason are false.
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Step 1. CH3-C(COOC2H5)=CH-COOH has two candidate principal groups, -COOH (a free acid) and -COOC2H5 (an ester); -COOH ranks higher in the functional-group precedence order, so it is the principal group and must be numbered C1.

Step 2. Numbering from the COOH end: C1 = COOH, C2 = CH (double-bonded), C3 = C bearing the -COOC2H5 substituent (double-bonded to C2), C4 = CH3.

Step 3. This gives the substituent name '3-carbethoxy' (the common/retained name for -COOC2H5 as a substituent) on a 'but-2-enoic acid' parent -- exactly matching the assertion's given name, 3-carbethoxy-2-butenoic acid. The assertion is TRUE. …

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