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Choose the Best Answer · Q7

Q.An ideal gas expands from the volume of 1×10−3 m31\times10^{-3}\ \text{m}^3 to 1×10−2 m31\times10^{-2}\ \text{m}^3 at 300 K against a constant pressure at 1×105 Nm−21\times10^{5}\ \text{Nm}^{-2}. The work done is

(a) – 900 J
(b) 900 kJ
(c) 270 kJ
(d) – 900 kJ
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Step 1. This is a single-step (irreversible) expansion against a constant external pressure, so w=−PextΔVw=-P_{ext}\Delta V (Section ~7.2.6, work done BY the system on expansion is negative).

Step 2. ΔV=Vf−Vi=1×10−2−1×10−3=9×10−3m3\Delta V=V_f-V_i=1\times10^{-2}-1\times10^{-3}=9\times10^{-3}\\ \text{m}^3. …

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