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Write Brief Answer · Q33

Q.Calculate the standard heat of formation of propane, if its heat of combustion is −2220.2-2220.2 kJ mol−1^{-1}. The heats of formation of CO2(g)CO_2(g) and H2O(l)H_2O(l) are −393.5-393.5 and −285.8-285.8 kJ mol−1^{-1} respectively.

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Step 1. C3H8(g)+5O2(g)→3CO2(g)+4H2O(l)C_3H_8(g)+5O_2(g)\rightarrow3CO_2(g)+4H_2O(l), ΔHC=−2220.2\Delta H_C=-2220.2 kJ mol−1^{-1}; using ΔHC=∑ΔHf(products)−∑ΔHf(reactants)\Delta H_C=\sum\Delta H_f(\text{products})-\sum\Delta H_f(\text{reactants}): −2220.2=[3(−393.5)+4(−285.8)]−[ΔHf(C3H8)+0]-2220.2=[3(-393.5)+4(-285.8)]-[\Delta H_f(C_3H_8)+0].

Step 2. Compute the products sum: 3(−393.5)=−1180.53(-393.5)=-1180.5; 4(−285.8)=−1143.24(-285.8)=-1143.2; total =−2323.7=-2323.7 kJ. …

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