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Q.State the various statements of second law of thermodynamics.

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Step 1. Entropy statement: the entropy of an isolated system increases during a spontaneous process; for an irreversible process ΔStotal>0\Delta S_{total}>0, while for a reversible process ΔStotal=0\Delta S_{total}=0.

Step 2. Kelvin-Planck statement: it is impossible to construct a machine that absorbs heat from a hot source and converts it completely into work by a cyclic process, without transferring part of that heat to a cold sink -- explaining why no heat engine can be 100% efficient.

Step 3. Clausius statement: it is impossible to transfer heat from a cold reservoir to a hot reservoir without doing some (external) work. …

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