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Write Brief Answer · Q15

Q.The equilibrium constant of a reaction is 10, what will be the sign of ΔG\Delta G? Will this reaction be spontaneous?

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Step 1. The Van't Hoff equation (Section 7.11.2) relates ΔG0\Delta G^0 and KeqK_{eq}: ΔG0=−RTln⁡Keq=−2.303RTlog⁡Keq\Delta G^0=-RT\ln K_{eq}=-2.303RT\log K_{eq}.

Step 2. Since Keq=10>1K_{eq}=10>1, log⁡Keq=log⁡10=1\log K_{eq}=\log10=1, a POSITIVE number.

Step 3. With the leading minus sign, ΔG0=−2.303RT(1)\Delta G^0=-2.303RT(1), which is NEGATIVE for any positive TT. …

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