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I. Multiple Choice Questions · Q14

Q.For a given gas molecule at a fixed temperature, the area under the Maxwell-Boltzmann distribution curve is equal to

(a) PVkT\dfrac{PV}{kT}
(b) kTPV\dfrac{kT}{PV}
(c) PNkT\dfrac{P}{NkT}
(d) PVPV
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Step 1. From Section 9.2.8, the Maxwell-Boltzmann distribution function dNv/dvdN_v/dv describes how many molecules have speeds in a narrow range around vv; integrating (summing) over ALL possible speeds gives back the total number of molecules NN in the sample -- this is exactly what 'the area under the curve' means.

Step 2. The ideal gas equation is PV=NkTPV=NkT, which rearranges to N=PVkTN=\dfrac{PV}{kT}.

Step 3. So the area under the Maxwell-Boltzmann distribution curve, being equal to NN, is also equal to PVkT\dfrac{PV}{kT}. …

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