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Write Brief Answer · Q19

Q.In a fuel cell, H2\text{H}_2 and O2\text{O}_2 react to produce electricity. In the process, H2\text{H}_2 gas is oxidised at the anode and O2\text{O}_2 gas is reduced at the cathode. If 44.8 litres of H2\text{H}_2 at 25°C and 1 atm pressure reacts in 10 minutes, what is the average current produced? If the entire current is used for electrodeposition of Cu from Cu2+\text{Cu}^{2+}, how many grams of Cu are deposited?

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Step 1. Moles of H2\text{H}_2 reacted: using the standard molar volume convention (22.4 L/mol), n(H2)=44.8/22.4=2n(\text{H}_2) = 44.8/22.4 = 2 mol.

Step 2. At the anode, H2→2H++2e−\text{H}_2 \rightarrow 2\text{H}^++2e^- (in the acidic-medium form; equivalently the alkaline form releases the same 2 electrons per H₂), so 2 mol H2\text{H}_2 releases 2×2=42\times2 = 4 mol electrons.

Step 3. Charge: Q=4×96500=386000Q = 4\times96500 = 386000 C. Time: t=10×60=600t = 10\times60=600 s. Average current: I=Q/t=386000/600≈643.3I = Q/t = 386000/600 \approx 643.3 A. …

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