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Question 84 of 111

Q.What are 'fuel cells'? Write cathode and anode reaction in a fuel cell.

Maharashtra MsbshseMaharashtra HSC (MSBSHSE) Board 2017Subjective· 2mImportance★★★★★
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Fuel cells generate electricity by continuously oxidising a fuel gas at the anode and reducing oxygen at the cathode, over a KOH electrolyte.

A fuel cell is a galvanic (voltaic) cell in which the reactants — a fuel such as hydrogen, methane or methanol, and an oxidant such as oxygen or air — are fed in continuously from outside, so the cell keeps generating electrical energy as long as the supply lasts, without needing to be recharged like an ordinary battery. The H2H_2–O2O_2 fuel cell is the classic example: two porous carbon electrodes (impregnated with catalysts like Pt/Pd) are dipped in concentrated aqueous KOH; hydrogen gas is bubbled at the anode and oxygen gas at the cathode.

Anode (oxidation): 2H2(g)+4OH−(aq)→4H2O(l)+4e−2H_2(g) + 4OH^-(aq) \rightarrow 4H_2O(l) + 4e^-

Cathode (reduction): O2(g)+2H2O(l)+4e−→4OH−(aq)O_2(g) + 2H_2O(l) + 4e^- \rightarrow 4OH^-(aq)

Overall cell reaction: 2H2(g)+O2(g)→2H2O(l)2H_2(g) + O_2(g) \rightarrow 2H_2O(l)

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