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Exercise · Q20

Q.Describe the basic structural unit found in all silicates. How do orthosilicates, chain silicates and sheet silicates differ in the way this unit is linked together?

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Every silicate mineral, however structurally elaborate, is ultimately built from a single repeating unit: the SiO44−\text{SiO}_4^{4-} tetrahedron, in which a central, sp3sp^3-hybridised silicon atom is covalently bonded to four oxygen atoms occupying the corners of a regular tetrahedron. The differences between silicate types arise purely from how many corner oxygens neighbouring tetrahedra share with each other. In an orthosilicate, the tetrahedra share no corners at all — each SiO44−\text{SiO}_4^{4-} unit stands isolated, its negative charge balanced by surrounding metal cations (e.g. olivine). In a chain silicate (pyroxene-type), each tetrahedron shares exactly two of its four corner oxygens with adjacent tetrahedra, linking them into an infinite, extended one-dimensional chain, with the repeating unit working out to (SiO3)2−(\text{SiO}_3)^{2-} per silicon. In a sheet silicate, each tetrahedron shares three of its four corners with its neighbours, extending the linkage into a two-dimensional p …

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