Exercises · 9.25
Q.Write chemical reactions to justify that hydrogen peroxide can function as an oxidising as well as reducing agent.
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Start your 14-day free trial to unlock the full solution →Hydrogen peroxide has an intermediate oxidation state of oxygen (−1), so it can either be reduced further (to −2 in H2O, acting as an oxidising agent) or oxidised (to 0 in O2, acting as a reducing agent), depending on the other reactant.
As an oxidising agent — H2O2 oxidises lead(II) sulphide to lead(II) sulphate (used to restore blackened lead-based paintings, converting black PbS back to white PbSO4):
It can also oxidise Fe²⁺ to Fe³⁺:
As a reducing agent — H2O2 reduces acidified potassium permanganate, itself being oxidised to O2 gas:
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