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Exercises · 9.8

Q.What do you understand by

(i) electron-deficient,
(ii) electron-precise, and
(iii) electron-rich compounds of hydrogen? Provide justification with suitable examples.
Telangana TsbieTextbookSubjectiveImportance★★★★★est
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Covalent hydrides of p-block elements (groups 13–17) are classified by comparing the number of valence electrons of the central atom with the number needed to form simple 2-centre-2-electron bonds to all the H atoms and complete an octet.

  1. Electron-deficient hydrides: these are hydrides in which the central atom has fewer electrons available than would be needed to form conventional bonds to satisfy an octet using normal 2-electron bonds. Example: diborane, B2H6 — boron (group 13) has only 3 valence electrons, so a simple Lewis structure would leave boron with an incomplete octet (only 6 electrons). Such molecules typically achieve extra stability through unusual bonding, e.g. 3-centre-2-electron ("banana") bridge bonds in B2H6, and behave as strong Lewis acids.
  2. Electron-precise hydrides: the central atom has exactly the number of electrons required to form the normal number of 2-electron covalent bonds and complete its octet, with no lone pairs left over. Example: CH4 (methane) — carbon's 4 valence electrons form 4 C–H bond pairs, fully satisfying the octet with nothing left over. Other group 14 hydrides (SiH4, GeH4) are similarly electron-precise. …

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