Q.Why are halogens strong oxidising agents?
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Start your 14-day free trial to unlock the full solution →Step 1: The oxidation process.
A halogen acts as an oxidising agent by accepting electrons and being reduced to halide ions:
This overall process can be broken into three energetic steps: (i) breaking the X–X bond,
(ii) electron gain by each X atom,
(iii) hydration of the resulting ion.
Step 2: Low bond dissociation enthalpy.
The X–X bond in halogens is relatively weak (especially for ), so relatively little energy is needed to generate free halogen atoms as the first step towards accepting electrons.
Step 3: High (negative) electron gain enthalpy.
Halogens have a strong tendency to gain one electron and complete a stable octet, releasing a large amount of energy (highly negative electron gain enthalpy), which strongly favours formation of .
Step 4: High hydration enthalpy.
The small, singly-charged ions are strongly hydrated (or solvated) in aqueous/other solution, releasing a large hydration enthalpy that further stabilises the ion once formed.
Step 5: Net effect. …
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