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Example · Example 1

Q.Write the IUPAC name of (CH3)2CHCH2CH(CH3)2(\text{CH}_3)_2\text{CHCH}_2\text{CH}(\text{CH}_3)_2.

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The longest continuous chain running through the structure is five carbons long, so the parent name is pentane. Numbering from either end places a methyl substituent on C2 and another on C4 (numbering from the other end would give 2,4 as well, by symmetry, so either direction gives the same, lowest locant set). Since the same substituent (methyl) appears twice, it is cited once with the prefix 'di-' and both locants: 2,4-dimethyl. Combining gives 2,4-dimethylpentane.

✓Final answer

The compound is 2,4-dimethylpentane.

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