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Example · Example 11

Q.Describe the hybridisation, geometry and bond angles at the double-bond carbons of ethene, and explain why the molecule is planar.

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Each carbon in ethene, CH2=CH2\text{CH}_2{=}\text{CH}_2, mixes one ss and two pp orbitals into three equivalent sp2sp^2 hybrid orbitals, arranged in a single plane at 120°120° to one another (trigonal planar geometry), leaving one unhybridised pp orbital perpendicular to that plane. Two of each carbon's three sp2sp^2 orbitals form sigma bonds to its two hydrogens, and the third forms a sigma bond, head-on, to the other carbon's sp2sp^2 orbital. Because all these sigma bonds lie in the same plane on both carbons, the whole H2C=CH2\text{H}_2\text{C=CH}_2 skeleton -- both carbons and all four hydrogens -- is forced into one plane, with H–C–H\text{H--C--H} and H–C–C\text{H--C--C} bond angles close to the ideal 120°120°. Separately, the two carbons' unhybridised pp orbitals, both perpendicular to this plane, overlap sideways to form the pi bond; this sideways overlap can only be maintained if the two pp orbitals stay parallel to each o …

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