Q.What is a fullerene? Describe the structure of (buckminsterfullerene), and explain how graphene is related to graphite. Name one property that makes graphene attractive for modern electronics.
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Start your 14-day free trial to unlock the full solution →A fullerene is a discrete, closed, hollow, cage-shaped carbon molecule, structurally distinct from both diamond's infinite 3-D network and graphite's stacked 2-D sheets. The best known example, ('buckminsterfullerene'), consists of exactly 60 carbon atoms, every one hybridised, arranged into a closed, roughly spherical cage built from 12 five-membered (pentagonal) rings and 20 six-membered (hexagonal) rings fused together — geometrically identical to the pattern of stitched panels on a classic football/soccer ball. Because is a genuine, finite molecule with a fixed molecular formula rather than an extended covalent network, it is soluble in certain organic solvents, a property neither diamond nor graphite shares.\n\nGraphene is, in essence, simply a single isolated layer taken from bulk graphite: one two-dimensional sheet of -hybridised carbon atoms arranged in the same fused-hexagon pattern as graphite, with the same delocalised -electron system running across the sheet, but now completely isolated as a standalone, one-atom-thick layer rather than stacked with countless other layers held by weak van der Waals forces. This isolation, combined with the inherent strength of the in-plane C–C bonding and the free delocalised electrons, gives graphene an outstanding combination of properties — it is extraordinarily strong for its very low weight, …
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