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Exercise · Q27

Q.What is the borax-bead test used for in qualitative inorganic analysis? Briefly describe what happens when borax is strongly heated and the resulting bead is touched to a coloured metal salt.

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The borax-bead test is a classic, simple qualitative-inorganic-analysis technique used to help identify certain transition metals in a sample. A small amount of solid borax, held on a loop of platinum or nichrome wire, is heated strongly in a flame; it first loses its water of crystallisation and swells up, then fuses into a clear, colourless, glassy bead. This bead is chemically a mixture of sodium metaborate (NaBO2\text{NaBO}_2) and boron oxide (B2O3\text{B}_2\text{O}_3), formed as the borax loses water on strong heating (the same kind of dehydration chemistry described for boric acid). While still hot, this glassy bead is touched to a small amount of a coloured metal salt and then reheated in the flame; the metal oxide dissolves into the molten borax-derived glass, and the resulting metaborate compound formed typically has a characteristic colour — for example, a blue bead commonly indicates the presence of cobalt, while a bead that is green in the oxidising flame commonly indicates chromium or copper — and the colour can sometimes differ depending on whether the bea …

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