Q.What is the borax-bead test used for in qualitative inorganic analysis? Briefly describe what happens when borax is strongly heated and the resulting bead is touched to a coloured metal salt.
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Start your 14-day free trial to unlock the full solution →The borax-bead test is a classic, simple qualitative-inorganic-analysis technique used to help identify certain transition metals in a sample. A small amount of solid borax, held on a loop of platinum or nichrome wire, is heated strongly in a flame; it first loses its water of crystallisation and swells up, then fuses into a clear, colourless, glassy bead. This bead is chemically a mixture of sodium metaborate () and boron oxide (), formed as the borax loses water on strong heating (the same kind of dehydration chemistry described for boric acid). While still hot, this glassy bead is touched to a small amount of a coloured metal salt and then reheated in the flame; the metal oxide dissolves into the molten borax-derived glass, and the resulting metaborate compound formed typically has a characteristic colour — for example, a blue bead commonly indicates the presence of cobalt, while a bead that is green in the oxidising flame commonly indicates chromium or copper — and the colour can sometimes differ depending on whether the bea …
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