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Example · Example 7

Q.Write a balanced equation for the laboratory preparation of diborane from boron trifluoride and lithium hydride, and state one characteristic chemical property of diborane (its behaviour towards air and water).

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A standard laboratory route to diborane uses lithium hydride as the hydride source, reacting it with boron trifluoride:\n2BF3+6LiH⟶B2H6+6LiF2\text{BF}_3 + 6\text{LiH} \longrightarrow \text{B}_2\text{H}_6 + 6\text{LiF}\nHere each boron is reduced from the +3+3 oxidation state it holds in BF3\text{BF}_3 down to a formal, average oxidation state within diborane, with fluoride displaced as lithium fluoride and hydride delivered to build up the B-H framework described in the previous answer. Diborane's most striking chemical property, a direct consequence of its electron-deficient, reactive structure, is that it is spontaneously flammable (pyrophoric) in air, igniting on contact with atmospheric oxygen and burning with a very hot flame; it is likewise rapidly and exothermically hydrolysed on contact with water, decomposing completely to boric acid and hydrogen gas:\nB2H6+6H2O⟶2B(OH)3+6H2\text{B}_2\text{H}_6 + 6\text{H}_2\text{O} \longrightarrow 2\text{B(OH)}_3 + 6\text{H}_2\nBoth reactions reflect diborane's high reactivity as an electro …

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