Q.Write a balanced equation for the laboratory preparation of diborane from boron trifluoride and lithium hydride, and state one characteristic chemical property of diborane (its behaviour towards air and water).
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Start your 14-day free trial to unlock the full solution →A standard laboratory route to diborane uses lithium hydride as the hydride source, reacting it with boron trifluoride:\n\nHere each boron is reduced from the oxidation state it holds in down to a formal, average oxidation state within diborane, with fluoride displaced as lithium fluoride and hydride delivered to build up the B-H framework described in the previous answer. Diborane's most striking chemical property, a direct consequence of its electron-deficient, reactive structure, is that it is spontaneously flammable (pyrophoric) in air, igniting on contact with atmospheric oxygen and burning with a very hot flame; it is likewise rapidly and exothermically hydrolysed on contact with water, decomposing completely to boric acid and hydrogen gas:\n\nBoth reactions reflect diborane's high reactivity as an electro …
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