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Exercise · Q11

Q.Define carbohydrates. On what structural basis are they classified as aldoses or ketoses?

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✓ Free question

Carbohydrates are defined as polyhydroxy aldehydes or polyhydroxy ketones, or larger molecules (such as disaccharides and polysaccharides) that yield such compounds when hydrolysed. Many, though not all, fit the general formula Cx(H2O)y\text{C}_x(\text{H}_2\text{O})_y.

Within this definition, a monosaccharide is classified purely by the type of carbonyl group it carries: if it has an aldehyde group (−CHO-\text{CHO}), it is called an aldose; if it has a ketone group (C=O\text{C}{=}\text{O}), it is called a ketose. Glucose (aldehyde at C1) is therefore an aldose, and fructose (ketone at C2) is a ketose.

✓Final answer

Carbohydrates are polyhydroxy aldehydes/ketones (or their hydrolysis products); the aldose/ketose split depends only on whether the carbonyl group present is an aldehyde or a ketone.

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