Q.What type of glycosidic linkage joins the glucose units of cellulose, and how does this differ from the linkage in amylose?
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Start your 14-day free trial to unlock the full solution →Cellulose is an unbranched, linear polymer of D-glucose units, joined together by -1,4-glycosidic linkages -- bonds running from C1 of one glucose unit to C4 of the next, in which the linkage oxygen sits on the 'beta' (above-the-ring) face at the anomeric carbon.
This is structurally very similar to amylose, which is also an unbranched chain of D-glucose units joined from C1 to C4 -- but amylose's linkage is instead an -1,4-glycosidic linkage, with the linkage oxygen on the opposite, 'alpha' (below-the-ring) face. So the two linkages connect exactly the same pair of ring carbons (C1 and C4); the only difference is the stereochemical orientation ( versus ) at the anomeric carbon forming the bond. This single stereochemical difference, small as it looks on paper, has a large structural consequence: it forces the -linked cellulos …
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