Example · Example 5
Q.Arrange methyl, primary (), secondary () and tertiary () carbocations in order of increasing stability, and give the reason for the trend.
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Start your 14-day free trial to unlock the full solution →A carbocation's empty orbital is stabilised by electron density donated from adjacent (and ) sigma bonds via hyperconjugation, and by the mildly electron-donating inductive effect of alkyl groups relative to hydrogen. Both effects grow with the number of alkyl groups directly attached to the cationic carbon: a tertiary cation has three such alkyl groups feeding it stabilisation by both mechanisms, a secondary cation has two, a primary cation has one, and the methyl cation, with no adjacent carbon at all, …
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