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Example · Example 32

Q.Propanenitrile (CH3CH2CN\text{CH}_3\text{CH}_2\text{CN}) is hydrolysed completely under acidic, aqueous conditions. Name the two products and write the balanced hydrolysis equation.

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Complete acidic hydrolysis of a nitrile proceeds through an amide intermediate to the carboxylic acid, with nitrogen expelled as ammonia (or, under acidic conditions, as the ammonium salt): CH3CH2CN+2H2O→H+,ΔCH3CH2COOH+NH3\text{CH}_3\text{CH}_2\text{CN} + 2\text{H}_2\text{O} \xrightarrow{\text{H}^+, \Delta} \text{CH}_3\text{CH}_2\text{COOH} + \text{NH}_3. The nitrile carbon is retained in the product, …

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