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Example · Example 4

Q.Nitrobenzene is reduced with granulated Sn\text{Sn} and concentrated HCl\text{HCl}. Name the final product and state how this reagent pair compares with Fe/HCl\text{Fe}/\text{HCl} in the extent of reduction achieved.

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Granulated tin with concentrated hydrochloric acid is another strong metal-acid reducing system, and it carries nitrobenzene fully through to aniline exactly as Fe/HCl\text{Fe}/\text{HCl} does: C6H5NO2+6[H]→Sn/HClC6H5NH2+2H2O\text{C}_6\text{H}_5\text{NO}_2 + 6[\text{H}] \xrightarrow{\text{Sn/HCl}} \text{C}_6\text{H}_5\text{NH}_2 + 2\text{H}_2\text{O}. The two reagent systems are practically interchangeable for this purpose and differ mainly in cost and in the handlin …

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