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Example · Example 8

Q.Describe the shape of the nitrogen atom in a simple aliphatic amine such as CH3NH2\text{CH}_3\text{NH}_2, and explain how this shape is responsible for the amine's basic character.

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Nitrogen in CH3NH2\text{CH}_3\text{NH}_2 forms three σ\sigma bonds (to one carbon and two hydrogens) and retains one lone pair, giving it four electron domains arranged tetrahedrally -- three bonds plus the lone pair occupying the fourth position, so the molecular shape (ignoring the lone pair) is PYRAMIDAL, exactly like ammonia. This lone pair points outward, away from the three substituents, and is fully available to accept an incoming proton (H+\text{H}^+) from an …

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