Q.What inspired N. Bartlett for carrying out reaction between Xe and PtF6?
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Start your 14-day free trial to unlock the full solution →Step 1: Bartlett's earlier discovery with oxygen.
Neil Bartlett had earlier discovered that platinum hexafluoride, , was a powerful enough oxidiser to oxidise molecular oxygen itself, forming the ionic compound dioxygenyl hexafluoroplatinate(V):
Step 2: The key numerical coincidence.
Bartlett noted that the first ionisation enthalpy of molecular (1175 kJ/mol, i.e. the energy to remove an electron from to form ) was remarkably close to the first ionisation enthalpy of the xenon atom (1170 kJ/mol).
Step 3: The reasoning/inspiration.
Since was strong enough to pull an electron away from (a species with an ionisation enthalpy of 1175 kJ/mol), and xenon's ionisation enthalpy (1170 kJ/mol) was almost the same (in fact very slightly lower), Bartlett reasoned that should be equally, if not more, capable of oxidising/ionising xenon.
Step 4: The outcome. …
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