Q.Arrange the following in the order of property indicated for each set:
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Start your 14-day free trial to unlock the full solution →Step 1: (i) Bond dissociation enthalpy of halogens.
The approximate bond enthalpies are F–F ≈ 155, Cl–Cl ≈ 242, Br–Br ≈ 192, I–I ≈ 151 kJ/mol. Fluorine's bond is anomalously weak (not the strongest, despite F being the smallest) because of strong lone-pair–lone-pair repulsion between the closely-spaced small F atoms; overall the order of increasing bond dissociation enthalpy is:
Step 2: (ii) Acid strength of hydrogen halides.
Down the group, the H–X bond becomes progressively weaker (longer, more diffuse orbital overlap) as X becomes larger, so the acid ionises more readily in water; acid strength therefore increases down the group:
(HF is a comparatively weak acid in water partly also due to strong hydrogen bonding/ion-pairing effects, reinforcing this trend.)
Step 3: (iii) Base strength of Group 15 hydrides. …
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