$PtCl_4 \cdot 2KCl$ doesn't give precipitate of AgCl with $AgNO_3$ solution. Write the structural formula and IUPAC name of the complex.

PtCl₄ · 2KCl doesn't give precipitate of AgCl with AgNO — CBSE Class 12 Chemistry 2025 PYQ

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PtCl_4 \cdot 2KCl

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Concept understanding — Coordination Compound Nomenclature

Coordination Compound Nomenclature: From Intuition to Precision

Imagine you're naming a person. You'd say "Ravi Sharma" — family name first, then given name. Coordination compounds have a similar logic, but the "family name" is the metal, and the "given names" are the groups attached to it. The rules are just a systematic way of writing that name so any chemist anywhere can draw the exact structure from it.

The Core Idea

A coordination compound has a central metal ion surrounded by molecules or ions called ligands. Think of the metal as the nucleus and ligands as planets orbiting it. The entire assembly (metal + ligands) is called the coordination sphere, and it's written inside square brackets: [Co(NH₃)₆]Cl₃.

The nomenclature rules tell you:

What order to list things
How to name each ligand
How to indicate the metal's oxidation state
How to handle the counter-ions outside the brackets

The Rules, Step by Step

1. Cation before anion (just like NaCl is sodium chloride)

If the complex ion is positive, it's named first. If it's negative, it's named last. Simple.

2. Within the coordination sphere: ligands first, then metal

This is the big rule. Ligands are named before the metal, in alphabetical order (ignoring prefixes like di-, tri-).

Note

Alphabetical order is based on the ligand's name, not its formula. So NH₃ (ammine) comes before H₂O (aqua), even though N comes after H in the alphabet.

3. Naming ligands

Ligand type	Name	Example
Neutral molecule (NH₃)	ammine	`[Co(NH₃)₆]³⁺` → hexaamminecobalt(III)
Neutral molecule (H₂O)	aqua	`[Cu(H₂O)₄]²⁺` → tetraaquacopper(II)
Neutral molecule (CO)	carbonyl	`[Ni(CO)₄]` → tetracarbonylnickel(0)
Negative ion (Cl⁻)	chloro	`[PtCl₆]²⁻` → hexachloroplatinate(IV)
Negative ion (CN⁻)	cyano	`[Fe(CN)₆]⁴⁻` → hexacyanoferrate(II)
Negative ion (OH⁻)	hydroxo	`[Al(OH)₄]⁻` → tetrahydroxoaluminate(III)

Watch out

ammine (with two m's) is for NH₃ as a ligand. amine (one m) is for organic compounds like ethylamine. Don't mix them up — exam setters love this trap.

4. Prefixes for multiple ligands

Use Greek prefixes: di-, tri-, tetra-, penta-, hexa-, hepta-, octa-.

If the ligand name already contains a number (like ethylenediamine), use bis-, tris-, tetrakis- instead.

Tip

[Co(en)₃]³⁺ is tris(ethylenediamine)cobalt(III), not triethylenediaminecobalt(III). The parentheses around the ligand name are mandatory when using bis/tris/tetrakis.

5. Oxidation state of the metal

Write it in Roman numerals in parentheses right after the metal name. No space.

[Fe(CN)₆]³⁻ → hexacyanoferrate(III) (iron is in +3 state)

6. If the complex is an anion, change the metal's ending

Metal	Anionic form
Cobalt	cobaltate
Copper	cuprate
Iron	ferrate
Nickel	nickelate
Platinum	platinate
Zinc	zincate

General pattern: [M(L)ₙ]Xₘ \to cation name = [prefix-ligands]metal(oxidation state) anion name = [prefix-ligands]metal ate (oxidation state)

Worked Examples

Example 1: K₃[Fe(CN)₆]

Cation: potassium (K⁺)
Complex anion: [Fe(CN)₆]³⁻
Ligands: 6 cyano → hexacyano
Metal: iron → ferrate (because it's an anion)
Oxidation state: Fe is +3 (since 6 CN⁻ = -6, total charge -3, so Fe must be +3)
Answer: Potassium hexacyanoferrate(III)

Example 2: [Co(NH₃)₅Cl]Cl₂

Cation: [Co(NH₃)₅Cl]²⁺
Ligands: 5 ammine + 1 chloro → alphabetical: ammine before chloro → pentaamminechloro
Metal: cobalt
Oxidation state: Co is +3 (5 NH₃ neutral, 1 Cl⁻ = -1, total +2, so Co = +3) …

Why this formula?

Coordination Compound Nomenclature: Why the Rules Work

Coordination compound nomenclature isn't about a single formula — it's a system of rules built on a few core principles. Let's understand the why behind each major rule, so you never have to memorise blindly.

1. The Central Idea: Ligands as "Guests" Around a Metal "Host"

A coordination compound has a central metal atom/ion surrounded by ligands (molecules or ions that donate electron pairs). The naming reflects this relationship:

Cation first, then anion (like normal ionic compounds)
Ligands named before the metal (because they modify the metal's identity)

Why?

In chemistry, we name the more electropositive part first (cation). The metal-ligand complex is treated as a single unit — the ligands are "attached" to the metal, so they come first in the complex name.

2. Key Rule: Ligand Order — Alphabetical, Not by Charge

Rule: Ligands are named in alphabetical order (ignoring prefixes like di-, tri-).

Why?

If we ordered by charge or size, the name would change every time a ligand is replaced.
Alphabetical order is universal and unambiguous — it doesn't depend on the metal or oxidation state.
Example: [Co(NH₃)₄Cl₂]⁺ is tetraamminedichlorocobalt(III) — "ammine" (a) before "chloro" (c).

3. Oxidation State: Why Roman Numerals?

Rule: The metal's oxidation state is written in Roman numerals in parentheses after the metal name.

Why?

The oxidation state tells you the charge on the metal after accounting for ligand charges.
Roman numerals avoid confusion with Arabic numbers (which are used for ligand counts).
Example: [Fe(CN)₆]³⁻ → hexacyanoferrate(III) — the iron is Fe³⁺, not Fe²⁺.

Derivation of oxidation state:

Let the complex charge = $Q$ , ligand charges = sum of ligand charges $L$ , number of ligands = $n$ .

Then:

\text{Metal oxidation state} = Q - L

For [Fe(CN)₆]³⁻: CN⁻ has charge -1, so $L = 6 \times (-1) = -6$ , $Q = -3$ .

\text{Fe oxidation state} = -3 - (-6) = +3

4. Anionic Ligands: The "-o" Ending

Rule: Anionic ligands (negative ions) end in -o (e.g., Cl⁻ → chloro, CN⁻ → cyano, OH⁻ → hydroxo).

Why?

This distinguishes them from neutral ligands (e.g., NH₃ → ammine, H₂O → aqua).
The suffix -o signals "this ligand came from an anion" — crucial for charge balance.

Common examples:

Anion	Ligand name
Cl⁻	chloro
CN⁻	cyano
OH⁻	hydroxo
SO₄²⁻	sulfato

5. Neutral Ligands: Special Names

Rule: Neutral ligands keep their molecular name, except for a few with special names:

NH₃ → ammine (not "ammonia")
H₂O → aqua
CO → carbonyl
NO → nitrosyl

Why?

"Ammine" avoids confusion with ammonia (NH₃) as a free molecule.
These special names are historical but standardised — you must memorise them for exams.

6. Prefixes: di-, tri-, tetra-, etc.

Rule: Use Greek prefixes to indicate the number of each ligand:

2 → di, 3 → tri, 4 → tetra, 5 → penta, 6 → hexa

Why?

Without prefixes, [Co(NH₃)₆]³⁺ would be "hexaamminecobalt(III)" — the "hexa" tells you there are six ammines.
For ligands with complex names (e.g., ethylenediamine), use bis-, tris-, tetrakis- to avoid confusion.

Example:

[Co(en)₃]³⁺ → tris(ethylenediamine)cobalt(III) — "tris" because "triethylenediamine" would sound like three ethylenediamine molecules (which is correct, but "tris" is clearer).

7. Anionic Complexes: The "-ate" Suffix …

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Because $PtCl_4 \cdot 2KCl$ gives no $AgCl$ precipitate with $AgNO_3$ , all six chlorides are locked inside the coordination sphere as ligands around $Pt^{4+}$ . The complex is $K_2[PtCl_6]$ , named potassium hexachloridoplatinate(IV).

The key to unlocking this problem lies in understanding what happens when silver nitrate meets a coordination compound. $AgNO_3$ is the classic test reagent for free (ionizable) chloride ions in solution. If chlorides sit outside the coordination sphere as counter-ions, they dissociate freely in water and immediately precipitate as white $AgCl$ . But chlorides bound directly to the metal center—locked inside the square brackets of the complex—remain trapped and give no precipitate.

The formula $PtCl_4 \cdot 2KCl$ tells us we have four chlorines associated with platinum and two potassium chlorides. The experimental observation—no precipitate—means none of these six chlorides are free. They must all be coordinated to the platinum.

Building the structure

Identify the metal and its oxidation state. Platinum is the central metal. Since all six chlorides are ligands (each $Cl^-$ carries a $-1$ charge) and the two potassium ions (each $K^+$ carries a $+1$ charge) balance the charge, we can write:

2(+1) + x + 6(-1) = 0

where $x$ is the oxidation state of platinum. Solving gives $x = +4$ . Platinum is in the $+4$ oxidation state.

Construct the coordination entity.

All six chlorides coordinate to $Pt^{4+}$ , forming the complex anion $[PtCl_6]^{2-}$ . The $2-$ charge arises because six $Cl^-$ ligands contribute $-6$ , and the metal contributes $+4$ , netting $-2$ .
Balance with counter-ions.

Two potassium cations, $K^+$ , sit outside the coordination sphere to neutralize the $2-$ charge. The correct formula is:

K_2[PtCl_6]

Note

The structural formula shows the coordination sphere in square brackets: $K_2[PtCl_6]$ . The geometry around $Pt^{4+}$ with six ligands is octahedral, though the question asks for the formula rather than a 3D sketch.

IUPAC nomenclature

The IUPAC system names the complex ion first (if anionic), then the counter-ion.

Name the ligands. …

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Same / Similar Concept — real previous-year questions on the same or a closely similar concept, not this exact question.

Showing the 12 most recent of 56 on this concept.

CBSE 2026Set 56/3/11 markMCQ
$[Co(en)_3]_2(SO_4)_3$
›Reveal solutionSolution
The complex cation $[Co(en)_3]^{n+}$ must balance three sulfate anions ( $SO_4^{2-}$ ); since ethylenediamine is neutral, cobalt carries +3.

Why oxidation numbers matter in coordination compounds

Oxidation state tells us the formal charge on the central metal after we've assigned all bonding electrons to the more electronegative atom. In coordination chemistry, we treat ligands as intact units: neutral ligands contribute zero, anionic ligands contribute their charge. The sum of oxidation states in the entire complex must equal its net charge.

The formula $[Co(en)_3]_2(SO_4)_3$ shows us a salt: two complex cations paired with three sulfate anions. Our job is to figure out what charge the cobalt must carry to make the arithmetic work.

Step-by-step determination

1. Identify the ionic components

The compound dissociates into:

Two $[Co(en)_3]^{n+}$ cations (where $n$ is unknown)

Three $SO_4^{2-}$ anions

2. Apply charge neutrality

The entire salt is neutral, so total positive charge equals total negative charge:
$2 \times (\text{charge on one cation}) = 3 \times 2$ $2n = 6$ $n = +3$
Each complex cation carries a +3 charge: $[Co(en)_3]^{3+}$ .

3. Determine cobalt's oxidation state within the cation

Now look inside $[Co(en)_3]^{3+}$ . Ethylenediamine ( $en = H_2NCH_2CH_2NH_2$ ) is a neutral bidentate ligand—it donates two lone pairs but carries no charge. Three $en$ ligands contribute:
$3 \times 0 = 0$
The oxidation state of cobalt plus the ligand contributions must equal the cation charge:
$x_{Co} + 0 = +3$
$x_{Co} = +3$ …
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CBSE 2026Set 56/2/11 markMCQ
$[Pt(NH_3)_2Cl_2]$
›Reveal solutionSolution
The complex $[Pt(NH_3)_2Cl_2]$ is neutral, so the oxidation state of Pt must be +2. Ligands are named alphabetically (ammine before chlorido), and the metal is named without a suffix. The correct IUPAC name is diamminedichloridoplatinum(II) — option (B).

The key to naming coordination compounds is to follow the IUPAC rules in order: identify the oxidation state of the metal, list ligands alphabetically (ignoring prefixes like di-, tri-), and then name the metal with its oxidation state in parentheses.

Let’s break this down step by step.

Determine the oxidation state of platinum.

The complex $[Pt(NH_3)_2Cl_2]$ is neutral — no overall charge.

$NH_3$ is a neutral ligand (charge 0).

$Cl$ is a negatively charged ligand (chlorido, charge –1). Let the oxidation state of Pt be $x$ . Then: $x + 2(0) + 2(-1) = 0 \implies x - 2 = 0 \implies x = +2$ . So platinum is in the +2 oxidation state.

Name the ligands in alphabetical order.

IUPAC rules: ligands are named alphabetically by their name (not by prefix).

$NH_3$ is called ammine (note the double 'm').

$Cl$ is called chlorido (the anionic ligand name for chloride). Alphabetically, "ammine" comes before "chlorido". So the ligand order is: diammine then dichlorido.

Name the metal.

Since the complex is anionic? No — it’s neutral. For neutral complexes, the metal is called by its usual name (platinum), followed by the oxidation state in Roman numerals in parentheses: platinum(II).

Assemble the full name.

Ligands first (with prefixes di- for two identical ligands), then metal + oxidation state:

diamminedichloridoplatinum(II). …
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CBSE 2026Set 56/2/11 markMCQ
$[Co(NH_3)_6]^{3+}$
›Reveal solutionSolution
A heteroleptic complex contains more than one type of ligand. Among the given options, only $[Co(NH_3)_4Cl_2]^+$ has two different ligands ( $NH_3$ and $Cl^-$ ), making (D) the answer.

The distinction between homoleptic and heteroleptic complexes is fundamental to coordination chemistry and comes down to ligand diversity.

A homoleptic complex (from Greek homo = same, leptos = taking) contains only one kind of ligand attached to the central metal ion. Think of it as a "uniform" coordination sphere where every ligand is identical.

A heteroleptic complex (from Greek hetero = different) contains two or more different types of ligands. The coordination sphere is "mixed."

This classification matters because heteroleptic complexes exhibit richer isomerism (geometrical, optical) and more varied chemical behavior than their homoleptic counterparts.

Now let's examine each option systematically:

Option (A): $[Co(NH_3)_6]^{3+}$

The cobalt(III) ion is surrounded by six ammonia molecules. Every ligand is $NH_3$ —no variation whatsoever. This is a textbook homoleptic complex.

Option (B): $[Cr(NH_3)_6]^{3+}$

Chromium(III) coordinated to six identical ammonia ligands. Again, uniform ligand environment. Homoleptic.

Option (C): $[Ni(H_2O)_6]^{2+}$

Nickel(II) surrounded by six water molecules. All ligands are the same. Homoleptic.

Option (D): $[Co(NH_3)_4Cl_2]^+$ …
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CBSE 2026Set ANNUAL1 markMCQ
$Q. The oxidation number of nickel in [Ni(CO)4] will be:$
(a) 1
(b) 0
(c) 2
(d) 3
›Reveal solutionSolution

CO is a neutral ligand, so the oxidation number of Ni in [Ni(CO)₄] is 0.

In a coordination compound, the oxidation number of the central metal is found by assigning charges to the ligands and balancing against the overall charge of the complex. Carbonyl (CO) is a neutral ligand — it donates a lone pair from carbon without carrying any charge itself. Since [Ni(CO)₄] is a ne …

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CBSE 2026Set ANNUAL1 mark
$Q. Write the formula of the coordination compound tetraamine aquachlorido cobalt (III) chloride.$
›Reveal solutionSolution

Build the octahedral coordination sphere from the ligands named, find the complex ion's net charge from the metal's oxidation state, then add counter-ions to balance that charge.

Naming breakdown: 'tetraammine' $\rightarrow$ 4 $NH_3$ ligands (neutral); 'aqua' $\rightarrow$ 1 $H_2O$ ligand (neutral); 'chlorido' $\rightarrow$ 1 $Cl^-$ ligand (anionic, $-1$ ); 'cobalt(III)' $\rightarrow$ central metal $Co^{3+}$ . Coordination number $=4+1+1=6$ (octahedral), consistent with typical cobalt(III) ammine complexes.

…

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CBSE 2026Set ANNUAL1 mark
$Q. Write answer in one word/sentence: Write chemical formula of Iron (III) hexacyanidoferrate (II).$
›Reveal solutionSolution

Iron(III) hexacyanidoferrate(II) is Fe4[Fe(CN)6]3.

The complex anion hexacyanidoferrate(II) is [Fe(CN)6]4- (Fe in +2, six CN- ligands). The counter-cation is iron(III), Fe3+.

…

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CBSE 2026Set ANNUAL1 mark
$Q. A complex has the composition Co(NH₃)₄BrCl₂. Conductance measurement shows that there are two ions per formula unit and on treatment with silver nitrate it forms a yellow precipitate. Write the IUPAC name of the complex compound.$
›Reveal solutionSolution
A yellow AgBr precipitate shows free Br⁻; two ions per formula unit fix the structure as [Co(NH₃)₄Cl₂]Br → tetraamminedichloridocobalt(III) bromide.

Deducing the structure:

The composition is $Co(NH_3)_4BrCl_2$ .

Conductance shows two ions per formula unit, so the complex ionises into one cation and one anion.

With $AgNO_3$ it gives a yellow precipitate, which is $AgBr$ (silver chloride is white). So it is bromide ( $Br^-$ ) that is the free, ionisable counter-ion outside the coordination sphere, while both chloride ions are coordinated (non-ionisable) inside.

Hence the formula is $[Co(NH_3)_4Cl_2]Br$ , giving the two ions $[Co(NH_3)_4Cl_2]^+$ and $Br^-$ .

…
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CBSE 2025Set 56/6/11 markMCQ
$[Co(ox)_3]^{3-}$
›Reveal solutionSolution
Optical activity in coordination complexes requires the absence of a plane of symmetry. Among the given options, $trans\text{-}[Co(en)_2Cl_2]^+$ has a centre of symmetry and a plane of symmetry, making it optically inactive. The correct answer is (C).

Why Optical Activity Matters in Coordination Chemistry

Optical activity is a property of chiral molecules — those that are non-superimposable on their mirror image. In coordination compounds, chirality arises from the spatial arrangement of ligands around the central metal ion. A complex is optically active if it lacks an improper axis of rotation (specifically, a plane of symmetry or a centre of symmetry). The classic test: if a complex and its mirror image cannot be superimposed, they are enantiomers, and the complex is optically active.

For octahedral complexes, chirality often appears when:

Bidentate ligands (like oxalate, ox $^{2-}$ , or ethylenediamine, en) create a helical twist.

The arrangement of different ligands breaks symmetry.

Let’s examine each option systematically.

1. $[Co(ox)_3]^{3-}$ — The Tris(oxalato) Complex

Oxalate ( $\text{ox}^{2-}$ ) is a bidentate ligand that forms a five-membered chelate ring. Three oxalate ions around Co(III) give an octahedral geometry. The complex has a propeller-like shape: each oxalate spans one edge of the octahedron, and the three rings are arranged in a helical fashion.

Think of it like a three-bladed fan. The complex exists as a pair of enantiomers — left-handed and right-handed helices. There is no plane of symmetry because the chelate rings lock the structure into a chiral twist. Therefore, $[Co(ox)_3]^{3-}$ is optically active.

Tip

Any octahedral complex with three identical bidentate ligands (like $[M(AA)_3]$ ) is always chiral — it’s a classic example of helical chirality. The same applies to $[Co(en)_3]^{3+}$ in option (D).

2. $cis\text{-}[Co(en)_2Cl_2]^+$ — The Cis Isomer

Here, two ethylenediamine (en) ligands and two chloride ligands surround Co(III). The “cis” prefix means the two chlorides are adjacent (90° apart). In this geometry, the two en ligands are not equivalent in space — they create a non-superimposable mirror image.

Draw the structure: the two en rings lie in roughly perpendicular planes. The cis arrangement of Cl atoms breaks any plane of symmetry. The complex is chiral, and indeed, $cis\text{-}[Co(en)_2Cl_2]^+$ has been resolved into enantiomers. So it is optically active.

Watch out

A common mistake is to think that any complex with two identical bidentate ligands is automatically chiral. That’s only true for the cis isomer — the trans isomer is different, as we’ll see next.

3. $trans\text{-}[Co(en)_2Cl_2]^+$ — The Trans Isomer …
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CBSE 2025Set ANNUAL1 mark
$Q. Write formula for co-ordination compound Potassium trioxalatochromate (III).$
›Reveal solutionSolution

Three bidentate oxalate ligands (each -2) plus Cr3+ gives a -3 complex ion balanced by 3 K+.

'Trioxalato' means three oxalate ( $C_2O_4^{2-}$ ) ligands (bidentate, each carrying charge $-2$ ); 'chromate(III)' means the central metal is chromium in the $+3$ oxidation state.

…

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CBSE 2025Set D1 markMCQ
$Q. The IUPAC name of complex compound [Co(NH3)6]Cl3 is$
(a) Hexa-ammine cobalt (III) chloride
(b) Hexa-ammine cobalt (II) chloride
(c) Hexa-ammine trichloridocobalt (III)
(d) None of these
›Reveal solutionSolution
[Co(NH3)6]Cl3 = hexaamminecobalt(III) chloride.

Rules of IUPAC nomenclature:

Name the cation first, then the anion.

Within the complex, ligands are named alphabetically before the metal.

NH3 as a ligand is 'ammine' (six of them -> hexaammine).

Oxidation state of Co: three Cl- give -3; overall neutral, so Co = +3, written as (III).

The chloride outside is the counter-anion. …
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CBSE 2025Set ANNUAL1 mark
$Q. Write IUPAC name of the K3[Cr(C2O4)3] complex.$
›Reveal solutionSolution
K3[Cr(C2O4)3] names as potassium tris(oxalato)chromate(III), found by first working out Cr's oxidation state from the ionic charges.

Step 1 - find oxidation state of Cr:

Oxalate (C2O4)^2- is a bidentate ligand with charge -2; there are 3 of them: total ligand charge = 3 x (-2) = -6.

3 K+ balance the complex anion's charge, so the complex ion [Cr(C2O4)3]^3- carries charge -3.

Let oxidation state of Cr = x: x + (-6) = -3, so x = +3.

Step 2 - construct the IUPAC name:

Cation (potassium) named first, unchanged. …
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CBSE 2025Set ANNUAL1 markMCQ
$Q. The oxidation state of Fe in [Fe(CN)₆]⁻³:$
(a) +3
(b) +2
(c) +4
(d) -3
›Reveal solutionSolution

Since each CN⁻ ligand carries a −1 charge and the complex ion has an overall charge of −3, the oxidation state of Fe works out to +3.

…

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Q.PtCl4⋅2KClPtCl_4 \cdot 2KClPtCl4​⋅2KCl doesn't give precipitate of AgCl with AgNO3AgNO_3AgNO3​ solution. Write the structural formula and IUPAC name of the complex.

Building the structure

IUPAC nomenclature

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Q. $PtCl_4 \cdot 2KCl$ doesn't give precipitate of AgCl with $AgNO_3$ solution. Write the structural formula and IUPAC name of the complex.

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