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Q.Using Bohr's atomic model, derive the expression for the radius of nthn^{th} orbit of the revolving electron in a hydrogen atom.

(OR)
(a) Write two main observations of photoelectric effect experiment which could only be explained by Einstein's photoelectric equation.
(b) Draw a graph showing variation of photocurrent with the anode potential of a photocell.
CBSECBSE Class XII Board 2020Subjective· 2mImportance★★★★★
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Part (a): Balancing Coulomb and centripetal forces and quantising angular momentum gives the nthn^{th} Bohr orbit radius rn=n2h2ε0πme2=n2a0r_n=\dfrac{n^2h^2\varepsilon_0}{\pi m e^2}=n^2a_0.

Part (b): Einstein's equation explains the threshold frequency and instantaneous emission; the photocurrent–anode-potential graph is zero at a negative stopping potential and saturates at positive potential.

Graph of photoelectric current versus anode (collector plate) potential for a photocell: current is zero for potentials more negative than the stopping potential -V0, rises smoothly as the potential increases through zero, and saturates at a constant value for sufficiently positive anode potential.
Graph of photoelectric current versus anode (collector plate) potential for a photocell: current is zero for potentials more negative than the stopping potential -V0, rises smoothly as the potential increases through zero, and saturates at a constant value for sufficiently positive anode potential.

Part (a)

Bohr's model treats the electron as orbiting the proton, held by Coulomb attraction, with only certain "allowed" orbits.

  1. Force balance. The electrostatic force is the centripetal force:

14πε0e2r2=mv2r⇒mv2=e24πε0r.(1)\frac{1}{4\pi\varepsilon_0}\frac{e^2}{r^2}=\frac{mv^2}{r}\quad\Rightarrow\quad mv^2=\frac{e^2}{4\pi\varepsilon_0 r}.\qquad(1)

  1. Quantisation. Angular momentum is an integer multiple of h/2πh/2\pi:

mvr=nh2π,n=1,2,3,…⇒v=nh2πmr.(2)mvr=\frac{nh}{2\pi},\qquad n=1,2,3,\dots\quad\Rightarrow\quad v=\frac{nh}{2\pi m r}.\qquad(2)

  1. Combine. Put vv from (2) into (1):

e24πε0r=m(nh2πmr)2=n2h24π2mr2.\frac{e^2}{4\pi\varepsilon_0 r}=m\left(\frac{nh}{2\pi m r}\right)^2=\frac{n^2h^2}{4\pi^2 m r^2}.

  1. Solve for rr. Multiply by r2r^2 and cancel 4π4\pi: e2rε0=n2h2πm⇒rn=n2h2ε0πme2.\frac{e^2 r}{\varepsilon_0}=\frac{n^2h^2}{\pi m}\quad\Rightarrow\quad r_n=\frac{n^2h^2\varepsilon_0}{\pi m e^2}. …

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