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Numericals · Q20

Q.Given the following data for incident wavelength and the stopping potential obtained from an experiment on photoelectric effect, estimate the value of Planck's constant and the work function of the cathode material. What is the threshold frequency and corresponding wavelength? What is the most likely metal used for emitter? Incident wavelength (in Å): 2536, 3650. Stopping potential (in V): 1.95, 0.5.

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Using eV0=hcλ−ϕ0eV_0=\dfrac{hc}{\lambda}-\phi_0, written with K≡hc/eK\equiv hc/e (in V·Å, since λ\lambda is in Å) as the unknown constant to be estimated from the data (not assuming the precise textbook value of h):\n\nV0=Kλ−ϕ0(all energies in eV/volts, λ in A˚)V_0 = \frac{K}{\lambda} - \phi_0 \quad\text{(all energies in eV/volts, } \lambda \text{ in Å)}\n\nFor the two data points (λ1=2536\lambda_1=2536 Å, V0,1=1.95V_{0,1}=1.95 V) and (λ2=3650\lambda_2=3650 Å, V0,2=0.5V_{0,2}=0.5 V):\n\n1.95=K2536−ϕ0,0.5=K3650−ϕ01.95 = \frac{K}{2536} - \phi_0, \qquad 0.5 = \frac{K}{3650} - \phi_0\n\nSubtracting: 1.45=K(12536−13650)=K×1.2035×10−41.45 = K\left(\dfrac{1}{2536}-\dfrac{1}{3650}\right) = K\times1.2035\times10^{-4}, so\n\nK=1.451.2035×10−4≈12048 V A˚K = \frac{1.45}{1.2035\times10^{-4}} \approx 12048\text{ V Å}\n\nConverting K to Planck's constant: h=K×e×10−10c=12048×1.6×10−19×10−103×108≈6.426×10−34 J s≈6.427×10−34 J sh = \dfrac{K\times e\times10^{-10}}{c} = \dfrac{12048\times1.6\times10^{-19}\times10^{-10}}{3\times10^8} \approx 6.426\times10^{-34}\text{ J s} \approx 6.427\times10^{-34}\text{ J s}, matching the book.\n\nThe work function follows from either data point, e.g. ϕ0=Kλ2−V0,2=120483650−0.5≈3.301−0.5=2.801\phi_0=\dfrac{K}{\lambda_2}-V_{0,2}=\dfrac{12048}{3650}-0.5\approx3.301-0.5=2.801 eV -- also matching the book exactly, and cross-checked with the first point: 120482536−1.95≈4.751−1.95=2.801\dfrac{12048}{2536}-1.95\approx4.751-1.95=2.801 eV. Consistent.\n\nNow, the threshold frequency and wavelength are where V0=0V_0=0: λ0=K/ϕ0=12048/2.801≈4301\lambda_0=K/\phi_0=12048/2.801\approx4301 Å, and ν0=c/λ0=(3×108)/(4301×10−10)≈6.974×1014\nu_0=c/\lambda_0=(3\times10^8)/(4301\times10^{-10})\approx6.974\times10^{14} Hz. Equivalently, ν0=ϕ0/h=(2.801×1.6×10−19)/(6.427×10−34)≈6.97×1014\nu_0=\phi_0/h=(2.801\times1.6\times10^{-19})/(6.427\times10^{-34})\approx6.97\times10^{14} Hz -- the SAME result, confirming this is the mathematically consistent threshold point for the h and ϕ0\phi_0 values derived above (and matching the book's own h and ϕ0\phi_0).\n\nA flagged discrepancy: the printed textbook answer key states the threshold as 6.761×10146.761\times10^{14} Hz and 4438 Å, but these two numbers are NOT what follows from the SAME h and ϕ0\phi_0 the book itself prints just before them (checking: ϕ0/h\phi_0/h …

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