Physics · Ch 3 — Kinetic Theory of Gases and Radiation
Stefan-Boltzmann Law of Radiation
Stefan-Boltzmann Law of Radiation
This section makes precise exactly how much thermal radiation a blackbody emits, as a function of its temperature.
History and statement. In 1879, Josef Stefan proposed an empirical relation, based on experimental observations, between the radiant power emitted per unit area by a perfect blackbody and its absolute temperature . Five years later, Boltzmann derived the same relation theoretically from thermodynamics -- so the result is known as the Stefan-Boltzmann law. It states: the rate of emission of radiant energy per unit area (the power radiated per unit area) of a perfect blackbody is directly proportional to the fourth power of its absolute temperature.
where is Stefan's constant, J msK (equivalently W mK), with dimensions .
A crucial feature of this law is that the power radiated by a perfect blackbody depends only on its temperature -- not on its colour, its material, or the nature of its surface. (This is, of course, specific to the idealised perfect blackbody; Section 3.12.1's emissivity captures how real, non-ideal surfaces fall short of this.)
If a perfect blackbody of surface area at temperature radiates for a time , the total energy emitted is (used directly in Example 3.6). For an ordinary (non-blackbody) surface with emissivity , the energy radiated per unit area per unit time is reduced proportionally:
(used in Example 3.7 to find an unknown filament temperature from a known emissivity and power).
Radiating into a warmer or cooler surroundings. If a perfect blackbody at temperature sits in surroundings at a different absolute temperature , it simultaneously radiates energy at rate per unit area and absorbs energy from the surroundings at rate per unit area (Prevost's theory of exchange, Section 3.12). Its net loss of energy per unit area per unit time is therefore
and for an ordinary body of emissivity ,
If instead (the body is cooler than its surroundings), this same expression, now negative, represents a net gain of thermal energy by the body per unit area per unit time (used in Example 3.8 to compare cooling rates of a sphere at two different temperatures against a common surrounding temperature, and in Example 3.9 to compare the total radiated powers -- and hence relative sizes -- of two blackbody stars). …
Internet my friend — links the textbook itself suggests:
- https://www.britannica.com/science/kinetic-theory-of-gases
- https://www.youtube.com/watch?v=XrAktUy3_3k
- https://www.youtube.com/watch?v=3tD7ZuqaZik
- https://www.youtube.com/watch?v=7BXvc9W97iU
- https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Maps/Map%3A_Physical_Chemistry_(McQuarrie_and_Simon)/01%3A_The_Dawn_of_the_Quantum_Theory/1.01%3A_Blackbody_Radiation_Cannot_Be_Explained_Classically …