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Physics · Class 12 Science

Ch 3Kinetic Theory of Gases and Radiation — Class 12 Physics, concept-first.

The state of a fixed mass of gas is completely specified by a small set of macroscopic quantities -- its pressure , volume , temperature , and internal energy -- and any equation relating these quantities for a given gas is called its equation of state.

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Chapter contents

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3.1

Introduction

The state of a fixed mass of gas is completely specified by a small set of macroscopic quantities -- its pressure , volume , temperature , and internal energy -- and any equation relating these quanti…

3.2

Behaviour of a Gas

A single stone thrown into the air has a motion that is straightforward to describe: Newton's laws of motion, applied to that one object, tell us exactly where it will be at any instant.

3.3

Ideal Gas and Real Gas

A gas that obeys the ideal gas equation at every pressure and every temperature is called an ideal gas.

3.4

Mean Free Path

The molecules of an ideal gas are in continuous, random motion of the same qualitative character as the Brownian motion studied earlier -- ceaseless, erratic, undirected motion with no molecule favour…

3.5

Pressure of Ideal Gas

This section derives, from first principles of Newtonian mechanics, how the macroscopic pressure exerted by a gas arises from the microscopic motion and collisions of its molecules.

3.6

Root Mean Square (rms) Speed

Equation from Section 3.5 can be rearranged to give the mean square speed of the gas molecules directly in terms of macroscopic quantities:

3.7

Interpretation of Temperature in Kinetic Theory

Equation can be rewritten as

3.8

Law of Equipartition of Energy

The kinetic energy of a single molecule, expressed component-wise, is

3.8.1

Degrees of Freedom

In the discussion of translational kinetic energy above, the molecule was implicitly free to move anywhere in three-dimensional space, needing three coordinates (, , ) and three velocity components (,…

3.8.2

Diatomic Molecules

A monatomic gas such as helium consists of single atoms, and a He atom -- being, for these purposes, effectively a point mass -- has only 3 translational degrees of freedom, and no others.

3.9

Specific Heat Capacity

When the temperature of a gas is raised even slightly, both its volume and pressure can change considerably depending on the conditions under which heating occurs.

3.9.1

Mayer's Relation

Setup. Consider one mole of an ideal gas enclosed in a cylinder by a light, frictionless, airtight piston, with pressure , volume and temperature .

3.10

Absorption, Reflection and Transmission of Heat Radiation

4 Q

Heat can be transferred by three distinct modes: conduction, convection and radiation. Conduction and convection both require a material medium -- heat cannot flow by these routes through a vacuum.

3.10.1

Interaction of Thermal Radiation and Matter

Let be the total thermal energy incident on the surface of an object in some time interval, and let , , be the respective amounts of that energy which are absorbed, reflected and transmitted.

3.11

Perfect Blackbody

A body that absorbs the entire radiant energy incident on it -- i.e. in the notation of Section 3.10.1 -- is called an ideal or perfect blackbody.

3.11.1

Ferry's Blackbody

A simple, practical laboratory arrangement for realising a near-perfect blackbody was designed by Ferry.

3.12

Emission of Heat Radiation

In 1792, Pierre Prevost published what is now called the theory of exchange of heat: every body, at every temperature above absolute zero (0 K), continuously radiates thermal energy, and simultaneousl…

3.12.1

Coefficient of Emission or Emissivity

The coefficient of emission, or emissivity, , of a given surface is defined as the ratio of that surface's emissive power to the emissive power of a perfect black surface, both measured at the same te…

3.13

Kirchhoff's Law of Heat Radiation and its Theoretical Proof

Kirchhoff's law of thermal radiation connects a body's emissive power to its absorptive power, wavelength by wavelength, for a body in thermal equilibrium.

3.14

Spectral Distribution of Blackbody Radiation

The radiant energy emitted per unit area per unit time by a blackbody is not spread out evenly across all wavelengths -- it depends both on the body's temperature and on the wavelength under considera…

3.14.1

Wien's Displacement Law

2 Q

One of the clearest quantitative features of the blackbody spectral-distribution curves (Section 3.14, observation 4) is that the wavelength at which a blackbody's emissive power is maximum is inverse…

3.15

Stefan-Boltzmann Law of Radiation

This section makes precise exactly how much thermal radiation a blackbody emits, as a function of its temperature.

1. Choose the correct option.

The chapter-end exercises of the Balbharati Physics Std-XII textbook for Kinetic Theory of Gases and Radiation, in the book's own printed order and grouping: five multiple-choice questions, five short…

2. Answer in brief.

Questions 3–25

+Questions 3-2523 questions
  1. Q3When a gas is heated its temperature increases. Explain this phenomenon based on the kinetic theory of gases.Free
  2. Q4Explain, on the basis of kinetic theory, how the pressure of a gas changes if its volume is reduced at constant temperature.Free
  3. Q5Mention the conditions under which a real gas obeys the ideal gas equation.Free
  4. Q6State the law of equipartition of energy and hence calculate the molar specific heat of monatomic and diatomic gases at constant volume and…Preview
  5. Q7What is a perfect blackbody? How can it be realized in practice?Preview
  6. Q8State (i) Stefan-Boltzmann law and (ii) Wien's displacement law.Preview
  7. Q9Explain the spectral distribution of blackbody radiation.Preview
  8. Q10State and prove Kirchhoff's law of heat radiation.Preview
  9. Q11Calculate the ratio of mean square speeds of molecules of a gas at 30 K and 120 K.Preview
  10. Q12Two vessels A and B are filled with the same gas where the volume, temperature and pressure in vessel A are twice the volume, temperature an…Preview
  11. Q13A gas in a cylinder is at pressure P. If the masses of all the molecules are made one third of their original value and their speeds are dou…Preview
  12. Q14Show that the rms velocity of an oxygen molecule is $\sqrt{2}$ times that of a sulfur dioxide molecule at S.T.P.Preview
  13. Q15At what temperature will oxygen molecules have the same rms speed as helium molecules at S.T.P.? (Molecular masses of oxygen and helium are…Preview
  14. Q16Compare the rms speed of hydrogen molecules at 127 ºC with the rms speed of oxygen molecules at 27 ºC, given that the molecular masses of hy…Preview
  15. Q17Find the kinetic energy of 5000 cc of a gas at S.T.P., given the standard pressure is $1.013\times10^{5}$ N/m².Preview
  16. Q18Calculate the average molecular kinetic energy (i) per kmol (ii) per kg (iii) per molecule of oxygen at 127 ºC, given that the molecular wei…Preview
  17. Q19Calculate the energy radiated in one minute by a blackbody of surface area 100 cm² when it is maintained at 227 ºC. (Take Stefan's constant…Preview
  18. Q20Energy is emitted from a hole in an electric furnace at the rate of 20 W, when the temperature of the furnace is 727 ºC. What is the area of…Preview
  19. Q21The emissive power of a sphere of area 0.02 m² is 0.5 kcal s⁻¹ m⁻². What is the amount of heat radiated by the spherical surface in 20 secon…Preview
  20. Q22Compare the rates of emission of heat by a blackbody maintained at 727 ºC and at 227 ºC, if the blackbodies are surrounded by an enclosure (…Preview
  21. Q23Earth's mean temperature can be assumed to be 280 K. How will the curve of blackbody radiation look for this temperature? Find out $\lambda_…Preview
  22. Q24A small blackened solid copper sphere of radius 2.5 cm is placed in an evacuated chamber. The temperature of the chamber is maintained at 10…Preview
  23. Q25Find the temperature of a blackbody if its spectrum has a peak at (a) $\lambda_{max} = 700$ nm (visible), (b) $\lambda_{max} = 3$ cm (microw…Preview

Sample & Board Papers

Sample papers and previous-year board questions for this subject.

+Show 26 questions26 questions
  1. Q1Define 'emissive power' and 'coefficient of emission of a body'.Preview
  2. Q2For polyatomic molecules having 'f' vibrational modes, the ratio of two specific heats, $\dfrac{C_P}{C_V}$ is ______. (A) $\dfrac{1+f}{2+f}$…Preview
  3. Q3If the pressure of an ideal gas decreases by 10% isothermally, then its volume will ______. (a) decrease by 9% (b) increase by 7% (c) increa…Preview
  4. Q4Find the wavelength at which a black body radiates maximum energy, if its temperature is 427°C. (Wein's constant b = $2.898\times10^{-3}$ mK…Preview
  5. Q5Prove that root mean square velocity of gas molecule is directly proportional to the square root of its absolute temperature.Preview
  6. Q6A body cools at the rate of 0.5°C/minute when it is 25°C above the surroundings. Calculate the rate of cooling when it is 15°C above the sam…Preview
  7. Q7The kinetic energy per molecule of a gas at temperature T is ____. (a) $(3/2)RT$ (b) $(3/2)K_BT$ (c) $(2/3)RT$ (d) $(3/2)(RT/M)$Preview
  8. Q8State any 'four' assumptions of kinetic theory of gases.Preview
  9. Q9The specific heat capacity of water is (a) 8R (b) $\dfrac{7}{8}$R (c) 9R (d) $\dfrac{9}{7}$RPreview
  10. Q10What is perfectly black body? Explain Ferry's black body.Preview
  11. Q11Deduce Boyle's law using the expression for pressure exerted by the gas.Preview
  12. Q12Explain energy distribution spectrum of a black body radiation in terms of wavelength.Preview
  13. Q13The root mean square speed of the molecules of a gas is proportional to _____. [T = Absolute temperature of gas] (a) $\sqrt{T}$ (b) $1/\sqrt…Preview
  14. Q14The difference between the two molar specific heats of a gas is 9000 J/kg K. If the ratio of the two specific heats is 1.5, calculate the tw…Preview
  15. Q15Derive an expression for a pressure exerted by a gas on the basis of kinetic theory of gases.Preview
  16. Q16If 'n' is the number of molecules per unit volume and 'd' is the diameter of the molecules, the mean free path 'λ' of molecules is (a) $\sqr…Preview
  17. Q17Compare the rate of loss of heat from a metal sphere at 827°C with rate of loss of heat from the same at 427°C, if the temperature of surrou…Preview
  18. Q18On the basis of kinetic theory of gases obtain an expression for pressure exerted by gas molecules enclosed in a container on its walls.Preview
  19. Q19Draw a neat labelled diagram of Ferry's perfectly black body. Compare the rms speed of hydrogen molecules at 227°C with rms speed of oxygen…Preview
  20. Q20Which of the following materials belongs to diathermanous substance? (a) wood (b) iron (c) glass (d) copperPreview
  21. Q21Find kinetic energy of 1 litre of an ideal gas at S.T.P.Preview
  22. Q22Calculate the energy radiated in one minute by a perfectly black body of surface area 200 cm² when it is maintained at 127°C.Preview
  23. Q23State and prove Kirchhoff's law of heat radiation.Preview
  24. Q24In an ideal gas, molecules possess ______. (a) only kinetic energy (b) both kinetic energy and potential energy (c) only potential energy (d…Preview
  25. Q25Calculate the temperature at which the average kinetic energy of a molecule of a gas will be same as that of an electron accelerated through…Preview
  26. Q26Derive the relation between coefficient of absorption, coefficient of reflection and coefficient of transmission. Compare the r.m.s. speed o…Preview