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Exercises · 5.6

Q.What do you understand by activation of adsorbent? How is it achieved?

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Step 1 – Meaning. Since adsorption depends on surface area, "activation" is any treatment that increases the adsorbing capacity of a solid by increasing its effective surface area (or creating more active sites).

Step 2 – How it is achieved.

  • Increasing surface roughness/subdivision: rubbing, mechanically breaking, or making the surface porous exposes more surface.
  • Removing pre-adsorbed material: heating the adsorbent (e.g. wood charcoal heated to ~1273 K in vacuum or in a current of superheated steam) expels gases already adsorbed in its pores, uncovering a large fresh surface. Charcoal so treated is called activated charcoal and adsorbs strongly. …

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