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Exercise · Q17

Q.Write the structure of the repeat unit of terylene (polyethylene terephthalate), naming the type of linkage present.

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Terylene is formed by condensing ethylene glycol, HO–CH2CH2–OH\text{HO--CH}_2\text{CH}_2\text{--OH}, with terephthalic acid, p-HOOC–C6H4–COOHp\text{-HOOC--C}_6\text{H}_4\text{--COOH}; at each step, one −OH-\text{OH} condenses with one −COOH-\text{COOH} to form an ester linkage, −CO–O−-\text{CO--O}-, releasing water. Repeating this across both ends of every monomer gives the repeat unit [−O–CH2CH2–O–CO–C6H4–CO–]n\big[-\text{O--CH}_2\text{CH}_2\text{--O--CO--C}_6\text{H}_4\text{--CO--}\big]_n, in which the flexible two-carbon glycol bridge alternates with the rigid, planar benzene-ring-containing terephthalate unit, joined thro …

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