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Exercise · Q14

Q.Nylon-6,6 is formed from hexamethylenediamine and adipic acid.

(a) What small molecule is eliminated at each linking step?
(b) Why is the polymer named 'nylon-6,6'?
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At each step where an −NH2-\text{NH}_2 of hexamethylenediamine condenses with a −COOH-\text{COOH} of adipic acid to form the amide linkage, one molecule of water is eliminated as the by-product. The name 'nylon-6,6' records the carbon count of each monomer: hexamethylenediamine, H2N–(CH2)6–NH2\text{H}_2\text{N--}(\text{CH}_2)_6\text{--NH}_2, has 6 carbon atoms, and adipic acid, HOOC–(CH2)4–COOH\text{HOOC--}(\text{CH}_2)_4\text{--COOH}, also has 6 carbon atoms in total (the 4 −CH2−-\text{CH}_2- carbons plus the 2 carboxyl carbons). The two numbers, written in the order diamine-then-diacid, distinguish it from other nylons made from monomers with di …

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