Explain why non-biodegradable polymers such as polythene persist in the environment for a very long time, and why this is considered an environmental concern.

Question

Accepted Answer

Concept understanding — Biodegradable Polymers

Biodegradable Polymers

Think about a plastic bottle thrown into a landfill. It sits there for hundreds of years, unchanged. Now imagine a leaf falling from a tree. Within months, it's broken down by microbes and turned back into soil. The difference is biodegradability — the ability of a material to be decomposed by living organisms (bacteria, fungi) into natural, harmless substances like carbon dioxide, water, and biomass.

A biodegradable polymer is simply a polymer that can be broken down this way. Most synthetic polymers (like polyethylene, PVC, nylon-6,6) have strong carbon-carbon backbones that microbes cannot easily attack. Biodegradable polymers are designed with weaker linkages — often ester bonds ( $-COO-$ ) or amide bonds ( $-CONH-$ ) — that enzymes and water can cleave.

The Precise Definition

Important

A biodegradable polymer is a polymer that undergoes degradation by the action of microorganisms (bacteria, fungi, algae) under natural environmental conditions, yielding products such as $CO_2$ , $H_2O$ , and biomass, without leaving toxic residues.

The key is that degradation happens in the environment (soil, water, compost) within a reasonable time frame — not just in a laboratory.

Two Important Examples

PHBV (Poly- $\beta$ -hydroxybutyrate-co- $\beta$ -hydroxyvalerate)

This is a copolymer made by bacteria as a food reserve. It has ester linkages in its backbone:

\text{PHBV} = \text{poly}(\text{3-hydroxybutyrate-co-3-hydroxyvalerate})

The ester bonds are susceptible to hydrolysis by microbial enzymes. PHBV is used in medical implants (sutures, drug delivery) and packaging. When discarded, soil microbes break it down completely.

Nylon-2-nylon-6

This is a polyamide made from glycine ( $H_2N-CH_2-COOH$ ) and amino caproic acid ( $H_2N-(CH_2)_5-COOH$ ). Unlike conventional nylons (which have long methylene chains between amide groups), nylon-2-nylon-6 has a structure that microbes can digest:

\text{Structure: } [-NH-CH_2-CO-NH-(CH_2)_5-CO-]_n

The alternating short segments make the amide bonds accessible to enzymatic attack. It degrades in soil within weeks. …

Start your 14-day free trial to unlock the full solution →

Micro-organisms break down organic matter using enzymes that have evolved to recognise and hydrolyse SPECIFIC functional-group linkages found in natural biomolecules -- ester bonds in fats, amide bonds in proteins, glycosidic bonds in starch and cellulose. Polythene's backbone, however, is a purely saturated sequence of carbon-carbon single bonds with no such recognisable linkage anywhere along its length; no naturally-evolved microbial enzyme is equipped to attack an ordinary $\text{C--C}$ bond buried inside a bulky, largely water-insoluble solid plastic. As a result, polythene discarded in soil, landfill or the ocean is not converted back into simple natural products the way a biodegradable material (or PHBV) would be, and instead persists largely unchanged for a very long time -- commonly estimated at several hundred years under typical environmental conditions. Because global production and single-use disposal of such non-biodegradable plastics occurs on an enormous scale, this persistence accumulates over time into a serious and growing land and marine pollution problem (including microplastic fragmentation, wildlife ingestion, and bl …

Start your 14-day free trial to unlock the full solution →

Same / Similar Concept — real previous-year questions on the same or a closely similar concept, not this exact question.

CBSE 2023Set ANNUAL1 markMCQ
$Q. Which of the following is/are biodegradable polymer(s)?$
(a) PHBV
(b) Nylon-2-Nylon-6
(c) Nylon-6,6
(d) Both
(a) and (b)
›Reveal solutionSolution
PHBV and Nylon-2-Nylon-6 are biodegradable copolymers; ordinary Nylon-6,6 is a non-biodegradable synthetic polyamide.

PHBV (poly-beta-hydroxybutyrate-co-beta-hydroxyvalerate) is a copolymer of 3-hydroxybutanoic acid and 3-hydroxypentanoic acid, produced/degraded by micro-organisms — it is biodegradable and used in packaging and medical implants.

Nylon-2-Nylon-6 is an alternating polyamide copolymer of glycine (H2N-CH2-COOH) and 6-aminohexanoic acid — the amide linkages here are readily hydrolysed/degraded biologically, making it biodegradable. …
Start your 14-day free trial to see the full solution →
CBSE 2022Set ANNUAL1 mark
$Q. Write the name of biodegradable polyamide copolymer.$
›Reveal solutionSolution

Nylon-2-nylon-6 is the standard example of a biodegradable polyamide copolymer.

Nylon-2-nylon-6 is formed by the alternating condensation copolymerisation of glycine ( $H_2N$ – $CH_2$ – $COOH$ , an amino acid) and 6-aminohexanoic acid (ε-aminocaproic acid, $H_2N$ – $(CH_2)_5$ – $COOH$ ), giving repeating amide (peptide-like) linkages. Because i …

Start your 14-day free trial to see the full solution →
CBSE 2019Set ANNUAL1 mark
$Q. Write any one example of biodegradable polymer.$
›Reveal solutionSolution

Biodegradable polymers are broken down by microorganisms in the environment into simple, non-toxic products; PHBV is a well-known example used to make packaging films and orthopaedic devices.

Biodegradable polymers are polymers that can be decomposed by the action of biological agents (bacteria, enzymes) in the environment, breaking down into harmless, simple by-products (like CO2, H2O and biomass), unlike conventional plastics which persist for a very long time.

…

Start your 14-day free trial to see the full solution →
CBSE 2018Set ANNUAL1 mark
$Q. What are biodegradable polymers?$
›Reveal solutionSolution

A biodegradable polymer is one whose chain can be enzymatically broken down by microorganisms into simple, environmentally-safe products (CO₂, H₂O, biomass) rather than persisting in the environment for centuries like conventional plastics.

Most synthetic polymers (like polyethylene or PVC) have carbon–carbon backbones that microorganisms cannot easily attack, so they persist in landfills/oceans for very long periods, causing plastic pollution. Biodegradable polymers are specifically designed with hydrolysable linkages (usually ester or amide bonds, similar to those found in natural biomolecules) built into their backbone, so that soil/water bacteria can secrete enzymes that break these bonds, decomposing the polymer into small, harmless, naturally recyclable molecules.

…

Start your 14-day free trial to see the full solution →

Q.Explain why non-biodegradable polymers such as polythene persist in the environment for a very long time, and why this is considered an environmental concern.

🎓Unlock everything free for 14 days

Unlock everything free for 14 days