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Numerical · Q27

Q.Calculate the ionisation energy of the He+^+ ion (Z=2Z=2) in its ground state (n=1n=1).

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Using En=−13.6 Z2n2 eVE_n=-\dfrac{13.6\,Z^2}{n^2}\ \text{eV} (Example 6) with Z=2Z=2 (He+^+) and n=1n=1:

E1=−13.6×2212 eV=−13.6×4 eV=−54.4 eVE_1 = -\frac{13.6\times2^2}{1^2}\ \text{eV} = -13.6\times4\ \text{eV} = -54.4\ \text{eV}

The ionisation energy is the energy needed to remove the electron completely, i.e. to raise it from E1=−54.4E_1=-54.4 eV to E∞=0E_\infty=0 eV, so it equals the MAGNITUDE of the ground-state energy:

Ionisation energy=∣E1∣=54.4 eV\text{Ionisation energy} = |E_1| = 54.4\ \text{eV} …

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