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Example · Example 5

Q.Using Bohr's postulates, derive an expression for the radius of the nnth stationary orbit of an electron in a hydrogen-like atom of atomic number ZZ.

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Force-balance condition (Postulate 1): 14πϵ0Ze2r2=mv2r⇒v2=Ze24πϵ0mr\frac{1}{4\pi\epsilon_0}\frac{Ze^2}{r^2}=\frac{mv^2}{r} \Rightarrow v^2=\frac{Ze^2}{4\pi\epsilon_0mr}.

Quantisation condition (Postulate 2): mvr=nh2π⇒v=nh2πmr⇒v2=n2h24π2m2r2mvr=\frac{nh}{2\pi}\Rightarrow v=\frac{nh}{2\pi mr}\Rightarrow v^2=\frac{n^2h^2}{4\pi^2m^2r^2}.

Eliminating vv: n2h24π2m2r2=Ze24πϵ0mr⇒n2h24π2mr=Ze24πϵ0⇒r=ϵ0n2h2πmZe2\frac{n^2h^2}{4\pi^2m^2r^2}=\frac{Ze^2}{4\pi\epsilon_0mr} \Rightarrow \frac{n^2h^2}{4\pi^2mr}=\frac{Ze^2}{4\pi\epsilon_0} \Rightarrow r=\frac{\epsilon_0n^2h^2}{\pi mZe^2}

rn=ϵ0n2h2πmZe2\boxed{r_n = \frac{\epsilon_0n^2h^2}{\pi mZe^2}} …

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