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Q.Which of the following is not a transition metal ? (A) Sc (B) Ag (C) Hg (D) Cu

CBSECBSE Class XII Board 2026MCQ· 1mImportance★★★★★
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Transition metals are defined by having partially filled d-orbitals in their common oxidation states. Mercury (Hg) has a full d¹⁰ configuration in both its elemental and common +2 state, so it is not a transition metal. The correct answer is (C).

Why This Definition Matters

The classification of transition metals isn't about being a metal or having d-electrons — it's about partially filled d-orbitals in the atom or in any common ion. This is the IUPAC definition. If an element's d-subshell is completely full (d¹⁰) in all its common forms, it doesn't qualify, even if it sits in the d-block of the periodic table.

Let's check each option against this rule.

  1. Scandium (Sc, Z=21)

    Electronic configuration: [Ar] 3d14s2[\text{Ar}]\,3d^1 4s^2.

    Its common ion is Sc³⁺: [Ar][\text{Ar}] — the 3d orbital is empty.

    But the atom has a partially filled d-orbital (3d¹). The definition says "in the atom or in any common oxidation state." Since the atom itself has an incomplete d-subshell, Sc is a transition metal.

  2. Silver (Ag, Z=47)

    Configuration: [Kr] 4d105s1[\text{Kr}]\,4d^{10} 5s^1.

    Common ion: Ag⁺ → [Kr] 4d10[\text{Kr}]\,4d^{10} — full d-subshell.

    However, silver also forms Ag²⁺ (e.g., in AgF₂), which has 4d94d^9 — a partially filled d-orbital. Because at least one common oxidation state (Ag²⁺) has an incomplete d-subshell, Ag qualifies as a transition metal.

  3. Mercury (Hg, Z=80)

    Configuration: [Xe] 4f145d106s2[\text{Xe}]\,4f^{14} 5d^{10} 6s^2.

    Common ions: Hg²⁺ → [Xe] 4f145d10[\text{Xe}]\,4f^{14} 5d^{10} (full d¹⁰); Hg₂²⁺ (dimeric) also has each Hg with a full d¹⁰ core.

    Mercury does not form any stable ion with a partially filled d-orbital. Its d-subshell is always full. Therefore, Hg is not a transition metal.

  4. Copper (Cu, Z=29)

    Configuration: [Ar] 3d104s1[\text{Ar}]\,3d^{10} 4s^1.

    Common ions: Cu⁺ → 3d103d^{10} (full); Cu²⁺ → 3d93d^9 (partially filled).

    Since Cu²⁺ has an incomplete d-subshell, copper is a transition metal.

Watch out

A common mistake is to think that because Hg is a d-block element and a metal, it must be a transition metal. But the d-block includes two "exceptions": zinc, cadmium, and mercury — their d-orbitals are always full, so they are not transition metals. They are often called "post-transition metals" or simply d-block metals.

Tip

To quickly spot non-transition metals in the d-block, look for elements whose common ions have a d¹⁰ configuration. Zn²⁺ (3d¹⁰), Cd²⁺ (4d¹⁰), and Hg²⁺ (5d¹⁰) are the classic trio. If an element only forms d¹⁰ ions, it's out.

✓Final answer

The element that is not a transition metal is (C) Hg.

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