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Question

Q.Two statements are given – one labelled Assertion (A) and the other labelled Reason (R). Select the correct answer from the codes (a), (b),

(c) and
(d) below.
(a) Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
(b) Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A).
(c) Assertion (A) is true, but Reason (R) is false.
(d) Assertion (A) is false and Reason (R) is also false. Assertion (A) : The internal resistance of a cell is constant. Reason (R) : Ionic concentration of the electrolyte remains same during use of a cell.
CBSECBSE Class XII Board 2023MCQ· 1mImportance★★★★★
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Both statements are false: a cell's internal resistance increases as the electrolyte concentration changes and ions are consumed during discharge, making the correct answer (d).

Why internal resistance matters

The internal resistance of a cell arises from the opposition to ion flow within the electrolyte and at the electrode-electrolyte interfaces. If the cell were an ideal voltage source, it would have zero internal resistance. Real cells, however, have finite rr that affects the terminal voltage under load: V=E−IrV = \mathcal{E} - Ir, where E\mathcal{E} is the emf and II is the current drawn.

The question asks whether this internal resistance stays constant and whether the electrolyte concentration remains unchanged during use. Both claims touch on what happens inside a cell as it discharges.

Examining the Assertion

Assertion (A): The internal resistance of a cell is constant.

This is false. Internal resistance depends on several factors:

  1. Electrolyte concentration: As a cell discharges, chemical reactions consume the active materials. In a typical electrochemical cell, ions are converted or depleted, changing the ionic concentration of the electrolyte. Lower ion concentration means fewer charge carriers, which increases resistivity and thus internal resistance.

  2. Temperature: Internal resistance decreases with rising temperature (ions move more freely) and increases when the cell cools.

  3. Age and usage: Over time, electrode surfaces may become coated with reaction products (polarization), further increasing resistance.

  4. State of charge: A nearly exhausted cell has significantly higher internal resistance than a fresh one.

In practice, rr increases noticeably as a cell is used, which is why old batteries deliver lower terminal voltages under the same load.

Examining the Reason

Reason (R): Ionic concentration of the electrolyte remains same during use of a cell.

This is also false. During discharge, electrochemical reactions at the electrodes consume reactants and produce products, directly altering the electrolyte composition.

For example, in a lead-acid cell:

  • At the anode: Pb+SO42−→PbSO4+2e−\text{Pb} + \text{SO}_4^{2-} \to \text{PbSO}_4 + 2e^-
  • At the cathode: PbO2+4H++SO42−+2e−→PbSO4+2H2O\text{PbO}_2 + 4\text{H}^+ + \text{SO}_4^{2-} + 2e^- \to \text{PbSO}_4 + 2\text{H}_2\text{O} …

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