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Q.Why do we generally consider two specific heats for a gas?

Maharashtra MsbshseTextbookSubjectiveImportance★★★★★
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For solids and liquids, heating causes only a small, often negligible change in volume, so a single specific heat is an adequate description. For a gas, however (§7.6.2), even a modest temperature change is accompanied by a considerable change in BOTH volume and pressure -- gases are highly compressible/expansible. If a gas is heated while its PRESSURE is held constant, it is free to expand, and part of the heat supplied goes into doing WORK on the surroundings during that expansion, rather than only raising the gas's internal energy (and hence its temperature). If instead the gas is heated at constant VOLUME, it cannot expand, so ALL the heat supplied goes directly into raising its internal energy/temperature, with none spent on external work. Because of this extra work term at constant pressure, MORE heat is needed for the same 1-degree rise when pressure (not vol …

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