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Numericals · Q32

Q.A gas at 900°C is cooled until both its pressure and volume are halved. Calculate its final temperature.

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Initial temperature T1=900+273.15=1173.15 KT_1 = 900+273.15 = 1173.15\text{ K}. Since PVT=constant\dfrac{PV}{T}=\text{constant} (Eq. 7.7) for a fixed amount of gas, and both PP and VV are halved (P2=P1/2P_2=P_1/2, V2=V1/2V_2=V_1/2), the product P2V2=(P1/2)(V1/2)=P1V1/4P_2V_2 = (P_1/2)(V_1/2) = P_1V_1/4. Since P1V1/T1=P2V2/T2P_1V_1/T_1 = P_2V_2/T_2, we get $T_2 = T_1\ …

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