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MCQ · Q2

Q.A glass bottle completely filled with water is kept in the freezer. Why does it crack? (A) Bottle gets contracted (B) Bottle is expanded (C) Water expands on freezing (D) Water contracts on freezing

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Almost all liquids contract when they solidify, but water is a well-known exception (§7.5.3): as it freezes into ice, its volume actually INCREASES rather than decreases (this is why ice floats on water instead of sinking). A glass bottle completely filled with water and sealed in a freezer therefore has no room to accommodate the extra volume the water occupies once it becomes ice -- the expanding ice pushes outward on the rigid glass walls with enough force to crack the bottle. Options (A) and (B), about the bottle's own thermal contraction/expansion, are not the dominant effect here (and glass barely changes size compared to the water's freezing expansion); option (D) states the opposite of what actually happens to water on freezing. [!ANSWER] (C) Water expands on freezing

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