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Numericals · Q24

Q.A glass flask has volume 1×10⁻⁴ m³. It is filled with a liquid at 30 ºC. If the temperature of the system is raised to 100 ºC, how much of the liquid will overflow? (Coefficient of volume expansion of glass is 1.2×10⁻⁵ (ºC)⁻¹ while that of the liquid is 75×10⁻⁵ (ºC)⁻¹.)

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Given: V1=1×10−4 m3V_1 = 1\times10^{-4}\text{ m}^3, T1=30 °CT_1=30\,°\text{C}, T2=100 °CT_2=100\,°\text{C} so ΔT=70 °C\Delta T = 70\,°\text{C}, γglass=1.2×10−5 °C−1\gamma_{glass}=1.2\times10^{-5}\,°\text{C}^{-1}, γliquid=75×10−5 °C−1\gamma_{liquid}=75\times10^{-5}\,°\text{C}^{-1}. Using ΔV=γV1ΔT\Delta V = \gamma V_1 \Delta T (Eq. 7.17) for each: increase in the LIQUID's volume =75×10−5×1×10−4×70=5.25×10−6 m3= 75\times10^{-5}\times1\times10^{-4}\times70 = 5.25\times10^{-6}\text{ m}^3; increase in the GLASS container's own volume =1.2×10−5×1×10−4×70=8.4×10−8 m3= 1.2\times10^{-5}\times1\times10^{-4}\times70 = 8.4\times10^{-8}\text{ m}^3. Since the liquid expands more than its container, the excess spills out: overflow =5.25×10−6−0.084×10−6=5.166×10−6 m3=516.6×10−8 m3= 5.25\times10^{-6} - 0.084\times10^{-6} = 5.166\times10^{-6}\text{ m}^3 = 516.6\times10^{-8}\text{ m}^3, matching the book's printed answer exactly. [!ANSWER] Overflow = 516.6 × 10⁻⁸ m³

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