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Question 79 of 89

Q.The product of the following reaction is:
C2H5−C∥O−CH3→ΔH2/Ni?C_2H_5-\overset{O}{\underset{\|}{C}}-CH_3 \xrightarrow[\Delta]{H_2/Ni} ?

(a) CH3−CH2−CH2−CH2−OHCH_3-CH_2-CH_2-CH_2-OH
(b) CH3−CH∣OH−CH2−CH3CH_3-\underset{OH}{\underset{|}{CH}}-CH_2-CH_3
(c) CH3−CH2−CH2−CH3CH_3-CH_2-CH_2-CH_3
(d) CH3−CH2−CH2−COOHCH_3-CH_2-CH_2-COOH
Maharashtra MsbshseMaharashtra HSC (MSBSHSE) Board 2024MCQ· 1mImportance★★★★★
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H2H_2/Ni reduces the ketone C=O to give butan-2-ol, CH3CH(OH)CH2CH3CH_3CH(OH)CH_2CH_3.

C2H5−CO−CH3C_2H_5-CO-CH_3 is butan-2-one (ethyl methyl ketone). On catalytic hydrogenation (H2H_2/Ni, Δ\Delta), the carbonyl group C=OC=O is reduced to CH−OHCH-OH:

CH3CH2−CO−CH3→ΔH2/NiCH3CH2−CH(OH)−CH3CH_3CH_2-CO-CH_3 \xrightarrow[\Delta]{H_2/Ni} CH_3CH_2-CH(OH)-CH_3

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